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1. Introduction
1. Introduction
Introduction
Solar Energy
The Greenhouse Effect
2. Properties of Sunlight
2. Properties of Sunlight
2.1. Basics of Light
Properties of Light
Energy of Photon
Photon Flux
Spectral Irradiance
Radiant Power Density
2.2. Blackbody Radiation
2.3. Solar Radiation
The Sun
Solar Radiation in Space
2.4. Terrestrial Solar Radiation
Solar Radiation Outside the Earth's Atmosphere
Atmospheric Effects
Air Mass
Motion of the Sun
Solar Time
Declination Angle
Elevation Angle
Azimuth Angle
The Sun's Position
Sun Position Calculator
Sun's Position to High Accuracy
Solar Radiation on a Tilted Surface
Arbitrary Orientation and Tilt
2.5. Solar Radiation Data
Calculation of Solar Insolation
Measurement of Solar Radiation
Analysis of Solar Irradiance Data Sets
Typical Meteorological Year Data (TMY)
Making Use of TMY Data
Average Solar Radiation
Isoflux Contour Plots
Sunshine Hour Data
Cloud Cover Data
Satellite Irradiance
3. Semiconductors & Junctions
3. Semiconductors & Junctions
Introduction
3.1. Basics
Semiconductor Materials
Semiconductor Structure
Conduction in Semiconductors
Band Gap
Intrinsic Carrier Concentration
Doping
Equilibrium Carrier Concentration
3.2. Generation
Absorption of Light
Absorption Coefficient
Absorption Depth
Generation Rate
3.3. Recombination
Types of Recombination
Lifetime
Diffusion Length
Surface Recombination
3.4. Carrier Transport
Movement of Carriers in Semiconductors
Diffusion
Drift
3.5. P-n Junctions
Formation of a PN-Junction
P-N Junction Diodes
Bias of PN Junctions
Diode Equation
3.6. Diode Equations for PV
Ideal Diode Equation Derivation
Basic Equations
Applying the Basic Equations to a PN Junction
Solving for Depletion Region
Solving for Quasi Neutral Regions
Finding Total Current
Eg1: Wide Base Diode
Eg2: Narrow Base Diode
Summary
4. Solar Cell Operation
4. Solar Cell Operation
4.1. Ideal Solar Cells
Solar Cell Structure
Light Generated Current
Collection Probability
Quantum Efficiency
Spectral Response
The Photovoltaic Effect
4.2. Solar Cell Parameters
IV Curve
Short-Circuit Current
Open-Circuit Voltage
Fill Factor
Efficiency
Detailed Balance
Tandem Cells
4.3. Resistive Effects
Characteristic Resistance
Effect of Parasitic Resistances
Series Resistance
Shunt Resistance
Impact of Both Series and Shunt Resistance
4.4. Other Effects
Effect of Temperature
Effect of Light Intensity
Ideality Factor
5. Design of Silicon Cells
5. Design of Silicon Cells
Solar Cell Design Principles
5.1. Optical Properties
Optical Losses
Anti-Reflection Coatings
AR Coating Color
DLARC
Surface Texturing
Material Thickness
Light Trapping
Lambertian Rear Reflectors
5.2. Reducing Recombination
Recombination Losses
Current Losses Due to Recombination
Voltage Losses due to Recombination
Surface Recombination
5.3. Top Contact Design
Series Resistance
Base Resistance
Sheet Resistivity
Emitter Resistance
Contact Resistance
Finger Resistance
Optimization of Finger Spacing
Metal Grid Pattern
5.4. Solar Cell Structure
Silicon Solar Cell Parameters
Efficiency and Solar Cell Cost
6. Manufacturing Si Cells
6. Manufacturing Si Cells
First Photovoltaic devices
Early Silicon Cells
6.1. Silicon Wаfers & Substrates
Refining Silicon
Types Of Silicon
Single Crystalline Silicon
Czochralski Silicon
Float Zone Silicon
Multi Crystalline Silicon
Wafer Slicing
Other Wafering Techniques
6.2. Processing Technologies
Solid State Diffusion
6.3. Cell Fabrication Technologies
Screen Printed Solar Cells
Buried Contact Solar Cells
High Efficiency Solar Cells
Rear Contact Solar Cells
6.4. Solar Cell Production Line
Source Material
Growing Ingots
Sawing the Ingot into Bricks
Wafer Slicing
Texturing
Emitter Diffusion
Edge Isolation
Anti Reflection Coatings
Screen Print Front
Screen Print Rear Aluminium
Screen Print Rear Silver
Firing
Testing
Module
7. Modules and Arrays
7. Modules and Arrays
Introduction
7.1. Module Design
Module Structure
Module Materials
Packing Density
7.2. Interconnection Effects
Module Circuit Design
Mismatch Effects
Mismatch for Cells Connected in Series
Shading
Hot Spot Heating
Bypass Diodes
Mismatch for Cells Connected in Parallel
Mismatch Effects in Arrays
7.3. Temperature Effects
PV Module Temperature
Heat Generation in PV Modules
Heat Loss in PV Modules
Nominal Operating Cell Temperature
Thermal Expansion and Thermal Stresses
7.4. Other Considerations
Electrical and Mechanical Insulation
7.5. Lifetime of PV Modules
Degradation and Failure Modes
7.6. Module Measurement
Module Measurement without Load
Module Measurement with Load
8. Characterization
8. Characterization
Introduction
8.1 Measurement of Solar Cell Efficiency
Illumination Sources
Temperature Control
Electronics
Probing
8.2. Other IV Measurements
Dark IV Measurements
Jsc-Voc and Suns-Voc
8.3. IV Characterization
Measurement of Series Resistance
Double Diode Model
Measuring Ideality Factor
8.4. Optical Characterization
Reflectance
Spectral Response
Laser Beam Induced Current
8.5. Lifetime
Bulk Lifetime
Surface Recombination
Transient Measurements
Quasi-Steady-State Lifetime Measurements
General Lifetime Measurements
Effect of Trapping on Lifetime Measurements
8.6. Luminescence
Electroluminescence
8.7. Simulation
Introduction to Simulation
PC1D
Tandem Calculations
2D Modeling
SEM and EBIC
Four Point Probe Resistivity Measurements
9. Material Properties
9. Material Properties
General Properties of Silicon
Optical Properties of Silicon
Bi2S3
CZTSSe Theory and Fabrication
CdS
CdSe
CuInSe2
CuO
CuS
FeS2
Mg2Si
MnS
SnS
TiS2
ZnSe
10. Batteries
10. Batteries
Storage in PV Systems
10.2 Battery Basics
Oxidation/Reduction Reaction
Electrochemical Potential
Standard Potential
Nernst Equation
Basic Battery Operation
Ideal battery capacity
10.3 Battery Non-equilibrium
10.4. Battery Characteristics
Battery Efficiency
Battery Capacity
Battery Charging and Discharging Parameters
Battery Lifetime and Maintenance
Battery Voltage
Other Electrical Battery Parameters
Summary and Comparison of Battery Characteristics
10.5. Lead Acid Batteries
Characteristics of Lead Acid Batteries
Operation of Lead Acid Batteries
10.6. Other Battery Types
10.7 Function and Use of Storage
11. Appendices
11. Appendices
Solar Cell Efficiency Records
Standard Solar Spectra
Periodic Table
Units and Conversions
Physical Constants
Equations for Photovoltaics
Korean Version PDF
Equations
Flash Animations
Interactive Graphs
References
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List of Graphs
List of Graphs
Anti-Reflection Coatings
Blackbody Radiation
Calculation of Solar Insolation
Collection Probability
Diffusion
Diode Equation
Double Diode Model
Double Layer Anti Reflection Coatings
Effect of Light Intensity
Generation Rate
Impact of Both Series and Shunt Resistance
Jsc-Voc and Suns-Voc
Material Thickness
Measurement of Series Resistance
Measuring Ideality Factor
Mismatch for Cells Connected in Parallel
Module Circuit Design
Optimization of Finger Spacing
Quantum Efficiency
Series Resistance
Shunt Resistance
Solar Radiation on a Tilted Surface
Solid State Diffusion
Spectral Response
Transient Measurements